In this study, we demonstrated the effective acquisition of magnetic iron oxide (MIO) for As(V) adsorption by high-temperature pyrolysis of waste iron sludge from the water treatment plant under a confined environment without adding extra chemical reagents. The operating temperature and time in the pyrolysis process were optimized to improve the yield of MIO and its As(V) adsorption capacity. MIO500-2(500 °C, 2 h) had both relatively high yield and arsenic adsorption efficiency, which was characterized by XRD and XPS as mainly γ-Fe2O3 with small particle size (100-900 nm), significant mesopore (12.43 nm), high specific surface area (65.25 m2/g), and effective saturation magnetization intensity (14.45 emu/g). The maximum adsorption capacity was 14.2 ± 0.4 mg/g, and the removal rate could still reach about 80 % after five times of adsorbent regeneration. Considering this facile preparation route and its high yield, large-scale production of MIO from waste iron sludge is feasible, which is expected to provide a low-cost and efficient adsorbent for the treatment of arsenic-containing water in less economically developed areas.
Keywords: Arsenic remediation; Facile high-temperature pyrolysis; Iron sludge; Maghemite; Without adding extra chemical reagents.
Copyright © 2023. Published by Elsevier B.V.