Biomass-derived carbon materials are promising electrode materials for capacitive energy storage. Herein, inspired by the hierarchical structure of natural wood, carbon monoliths built up by interconnected porous carbon nanosheets with enriched vertical channels were obtained via zinc nitrate (Zn(NO3)2)-assisted synthesis and served as thick electrodes for capacitive energy storage. Zn(NO3)2 is proved to function as expansion agent, activator, dopant, and precursor of the template. The dense and micron-scale thickness walls of wood were expanded by Zn(NO3)2 into porous and interconnected nanosheets. The pore volume and specific surface area were increased by more than 430 %. The initial specific capacitance and rate performance of the optimized carbon monolith was approximately three times that of the pristine dense carbon framework. The assembled symmetric supercapacitor possessed a high initial specific capacitance of 4564 mF cm-2 (0-1.7 V) at -40 °C. Impressively, the robust device could be cycled more than 100,000 times with little capacitance attenuation. The assembled zinc-ion hybrid capacitor (0.2-2 V) delivered a large specific capacitance of 4500 mF cm-2 at -40 °C, approximately 74 % of its specific capacitance at 25 °C. Our research paves a new avenue to design thick carbon electrodes with high capacitive performance by multifunctional Zn(NO3)2 for low-temperature applications.
Keywords: Electrical double-layer capacitors; High mass loading; Low temperature; Thick carbon electrode; Zinc-ion hybrid capacitors.
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