Nanosheet-assembled transition metal sulfides nanoflowers derived from CoMo-MOF for efficient oxygen evolution reaction

Shudi Yu; Dongmei Liu; Cheng Wang; Jie Li; Rui Yu; Yong Wang; Jiongting Yin; Xiaomei Wang; Yukou Du

doi:10.1016/j.jcis.2023.10.006

Nanosheet-assembled transition metal sulfides nanoflowers derived from CoMo-MOF for efficient oxygen evolution reaction

J Colloid Interface Sci. 2024 Jan;653(Pt B):1464-1477. doi: 10.1016/j.jcis.2023.10.006. Epub 2023 Oct 2.

Authors

Shudi Yu¹, Dongmei Liu¹, Cheng Wang¹, Jie Li¹, Rui Yu¹, Yong Wang², Jiongting Yin¹, Xiaomei Wang³, Yukou Du⁴

Affiliations

¹ College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Renai Road, Suzhou 215123, PR China.
² College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Renai Road, Suzhou 215123, PR China. Electronic address: yowang@suda.edu.cn.
³ School of Chemical Biology and Materials Engineering, Suzhou University of Science and Technology, Suzhou 215009, PR China. Electronic address: wangxiaomei@mail.usts.edu.cn.
⁴ College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Renai Road, Suzhou 215123, PR China. Electronic address: duyk@suda.edu.cn.

PMID: 37804615
DOI: 10.1016/j.jcis.2023.10.006

Abstract

Oxygen evolution reaction (OER) is a multi-electron transfer process, whose intrinsic sluggish dynamic restricts the whole process of overall water splitting (OWS). To address this issue, a porous transition metal sulfide (TMS) catalyst with rich heterojunctions was prepared by vulcanization and trace Fe doping of CoMo-based metal-organic framework (MOF). In this work, the nanoflower composed of ultrathin 2D nanosheets anchored on a nickel foam presents a layered interface that contributes to the exposure of active regions. The resulting electrode denoted as Fe@CoMo₂S₄/Ni₃S₂/NF required a low overpotential (η₁₀ = 167 mV @ 10 mA cm^-2, η₅₀ = 260 mV @ 50 mA cm^-2) in 1.0 M KOH for OER and a small cell voltage (E = 1.513 V @ 10 mA cm^-2) to power OWS when coupled with commercial Pt/C. It also exhibited splendid morphological and chemical stability with virtually invariant polarization curve and flower-like appearance after 1000 CV cycles, as well as long-term durability over 100 h with a constant current density of 10 mA cm^-2. This work revealed the multi-anionic regulation mechanism in the surface reconstruction of sulfide electrocatalysts, and verified that Co/Mo/Ni-based oxysulfide was the true active substance of OER, which inspired the understanding and design of multi-anionic regulated electrocatalysts.

Keywords: Anionic regulation mechanism; Fe doping; Metal-organic framework (MOF); Oxygen evolution reaction; Transition metal sulfides.