Photodeformable polymer materials have a far influence in the fields of flexibility and intelligence. The stimulation energy is converted into mechanical energy through molecular synergy. Among kinds of photodeformable polymer materials, liquid crystalline polymer (LCP) photodeformable materials have been a hot topic in recent years. Chromophores such as azobenzene, α-cyanostilbene, and 9,10-dithiopheneanthracene have been widely used in LCP, which are helpful for designing functional molecules to increase the penetration depth of light to change physical properties. Due to the various applications of photodeformable polymer materials, there are many excellent reports in intelligent field. In this review, we have systematized LCP containing azobenzene into 3 categories depending on the degree of crosslinking liquid crystalline elastomers, liquid crystalline networks, and linear LCPs. Other structural, typical polymer materials and their applications are discussed. Current issues faced and future directions to be developed for photodeformable polymer materials are also summarized.
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