With the increase of urban building height, people pay more and more attention to the characteristics of pollutants in urban canopy height. This study combined the generalized additive model (GAM) and the observation-based model (OBM) to explore the vertical characteristics and drivers of ozone (O3) based on meteorology tower (200 m) data to quantify the effects of factors and photochemical reactions on O3 formation at different heights. The F values of GAM reflect the importance of each factor, indicating that NO (F is 33.99 in the peak season, 36.72 in the non-peak season) was the dominant driver of O3 and was more important in the lower layer (20-116 m). Temperature (F is 35.42) was the main contributor to O3 pollution in the peak season, especially for O3 in the upper layer (116-200 m). The net O3 production rate in the peak season was 1.47 times that in the non-peak season due to strong photochemical reactions and meteorological conditions. And the net O3 production rate decreased sharply with increasing height in the two seasons. Less net O3 production in the upper layer was accompanied by a higher O3 mixing ratio, which indicated that there was more background O3 in the upper layer. OBM model results showed that the reaction between hydroperoxyl radical (HO2) and NO was the primary contribution pathway, accounting for 54.00 % and 57.50 % in the peak and non-peak seasons, respectively. O3 formation was highly sensitive to VOCs, while NOx reduction could have positive or negative effects on O3 depending on the levels of hydroxyl radical (OH). The understanding of the formation mechanism of O3 and the influence of NO on O3 provides insights into the importance of anthropogenic activities at urban canopy heights in shaping the vertical structure of O3.
Keywords: Drivers; GAM analysis; OBM-MCM; Photochemical reaction; Vertical distribution.
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