It is noteworthy that cholesteric liquid crystal (CLC) platforms have been witnessed in high-performance circularly polarized luminescence (CPL) behaviors through the highly organized chiral co-assembled arrangement of achiral dyes. However, most CPL-active design strategies are closely relative to the helix co-assembly structure of CLC rather than achiral dyes. Herein, we developed an intriguing regulation strategy for CPL-active CLC materials. They were regulated using the orientational order parameter (SF ) of achiral dichroic dyes as an incisive probe for the order arrangement degree of achiral dyes in CLC media. The I-shaped phenothiazine derivative PHECN dye (SF =0.30) emitted a strong CPL signal (|glum |=0.47). In contrast, the T-shaped derivative (PHEBen) dye (SF =0.09) showed a weak circular polarization level (|glum |=0.07) at similar CLC textures. Most interestingly, this kind of dichroic PHECN dye with a higher SF could greatly improve the contrast ratio of CPL (Δglum =0.47) and emission intensity (ΔFL=46.0 %) at direct-current electric field compared with the T-shaped PHEBen (Δglum =0.07 and ΔFL=1.0 %) in CLC. This work demonstrates that an induced CPL emission can be mediated using achiral dichroic dye, which will open a new avenue for developing excellent CPL-active display materials.
Keywords: Achiral Dichroic Dye; Chiral Induction; Cholesteric Liquid Crystal; Circularly Polarized Emission.
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