Emerging Trends in nanostructured materials-coated screen printed electrodes for the electrochemical detection of hazardous heavy metals in environmental matrices

Abstract

Heavy metal ions (HMIs) have become a significant contaminant in recent years. The increase in heavy metal pollution is a serious situation, requiring progressively robust, fast sensing, highly sensitive, and suitable techniques for heavy metal detection. Compared to other classical analytical methods, electroanalytical techniques, especially stripping voltammetric techniques with modified screen-printed electrodes (SPEs), have several advantages, such as fast sensing, great sensitivity, specificity, and long-time stability. Therefore, these techniques are more suitable for HMI detection. In this review, the nanostructured materials used to coat SPEs for the electrochemical determination of HMI are summarized. Additionally, the electrode fabrication method, modification steps, and electroanalytical study of these materials are systematically discussed. Hence, this review will support the researchers in precisely evaluating the electrochemical HMIs detection through highly sensitive stripping voltammetric techniques using SPE modified with nanostructured carbon and their allotropes, metal, metal oxides and their nanocomposites as sensor materials. Moreover, modified electrodes real time detection of HMIs in different food and environmental samples were briefly discussed.

Keywords: Electrochemical detection; Heavy metal ions; Nanostructured materials; Real samples; Screen-printed electrode.