Determining the soil odor control area: A case study of an abandoned organophosphorus pesticide factory in China

Abstract

Currently, soil odor-active substance screening and evaluation methods for contaminated sites are underdeveloped, with unclear treatment objectives and areas. Consequently, some sites suffer from odor issues during and even after remediation. This study focused on an organophosphorus pesticide factory site in Guangdong Province, China. It established a method of determining the odorant control area using a comprehensive approach combining instrumental and olfactory soil sample analyses. The main odor-active substances identified were ethylbenzene, phenol, m, p-xylene, styrene, toluene, and o-xylene, with odorant control values (the limit of odor-active substance contents) of 35.2, 28.1, 8.0, 11.3, 40.2 and 89.3 mg/kg respectively. Instrumental analysis of soil samples revealed 11 sampling points where the main odor-causing substances exceeded standard levels. Among the substances, ethylbenzene (1.48E+04 mg/kg) had the highest content, exceeding the limit up to 421-fold. Olfactory analysis indicated 14 sampling points with odor intensity surpassing the standard (OI > 2). Based on the instrumental analysis results and the odorant control value, the initial estimated odor control area (area with the risk of odor nuisance) was 5.64E+03 m². Incorporating the olfactory analysis findings, the control area was adjusted by 1.25E+03 m², leading to a final calculated soil odor control area of 6.89E+03 m² for the study site. The comprehensive approach to analyzing soil samples for odor control can help evaluate the extent of soil odor pollution in contaminated sites and provide a scientific basis for effectively removing and managing odor-causing substances in soil.

Keywords: Instrumental analysis; Land; Odor-active substances; Olfactory analysis.