Batteries that are both high-energy-density and durable at sub-zero temperatures are highly desirable for deep space and subsea exploration and military defense applications. Our design incorporates a casting membrane technology to prepare a gallium indium liquid metal (LM)/fluoropolymer hybrid protective film on a lithium metal anode. The LM not only spontaneously forms a passivation alloy layer with lithium but also reduces the nucleation potential barrier and homogenizes the Li+ flux on the surface of the lithium anode. The fluoropolymer's polar functional groups (-C-F-) effectively induce targeted dispersion of gallium indium seeds, and the unique pit structure on the surface provides oriented sites for lithium plating. By implementing these strategies optimally, the protected lithium metal anode remains in operation at a current density of 20 mA cm-2 with an over-potential of about 50.4 mV after 500 h, and the full cells have a high capacity retention rate of up to 98.5% at a current density of 0.5 C after 100 cycles. Furthermore, the battery shows improved low temperature performance at -30 °C, validating the potential of the protective film to enable battery operation at sub-zero temperatures.
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