Influence of Silicon Additives on Tribological and Rheological Test Results for Vegetable Lubricants

Materials (Basel). 2023 Sep 16;16(18):6245. doi: 10.3390/ma16186245.

Abstract

This paper describes an investigation of the effects of silicone-containing additives on the tribological and rheological properties of various lubricant blends. Aerosil® and layered silicate were used to modify lubricants containing rapeseed, linseed and soy oil that were thickened with soap thickener. Tribological tests were carried out using a four-ball concentric contact tester. On the basis of the data obtained from the tribological studies of the selected lubricant blends, it was concluded that the addition of amorphous silica increased the anti-seizure and anti-wear properties of the tested lubricants. The addition of montmorillonite caused a significant increase in the values of the individual parameters determining the level of lubricating properties of the tested lubricants in comparison with the lubricants modified with the silica additive. Based on the results of the rheological tests of the studied lubricants, it was found that the applied additives caused a change in the dynamic viscosity and chemical structure of the tested lubricants, expressed by a change in the values of the G' and G″ indices. The main finding of this manuscript was to demonstrate that the use of montmorillonite and aerosil additives improves the functional properties of vegetable-based plastic lubricants. The performance of tribological and rheological tests is of great scientific importance, as it provides an insight into the interaction of siliceous additives with the results of tribological tests on vegetable-oil-based greases. These findings make it possible to determine the behaviour of the lubricant under load and add to the knowledge of vegetable greases.

Keywords: G′ and G″ modules; antiscuffing properties; antiwear properties; dynamic viscosity; flow curves; mean square displacement; vegetable lubricants; viscosity curves; yield point.

Grants and funding

The project was co-financed by the Targeted Grant of the Łukasiewicz Centre for Scientific Excellence 3/Ł-ITEE/CŁ/2021.