The reactivity of free 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene (MeIPr) and 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IDipp) in dichloromethane was investigated. MeIPr reacts relatively slowly and selectively with the solvent under the formation of imidazolium salt [MeIPrH]Cl, which was characterised through NMR and IR spectroscopy as well as single crystal X-ray diffraction. Through deuterium labelling experiments the reaction rate was determined. In contrast IDipp reacts unselectively to various imidazolium salts. Due to the slow decomposition rates of MeIPr and IDipp in CH2Cl2, reactions of the free carbenes with BeBr2 to [(MeIPr)BeBr2], [(MeIPr)2BeBr2] and [(IDipp)BeBr2] can be performed.