SO42- ions as a nucleophilic reagent: straightforward electrochemical access to organosulfates

Chen Li; Zhuo Chen; Xue-Yang Guo; Li-Rong Wen; Ming Li; Lin-Bao Zhang

doi:10.1039/d3cc03960a

SO₄^2- ions as a nucleophilic reagent: straightforward electrochemical access to organosulfates

Chem Commun (Camb). 2023 Oct 10;59(81):12164-12167. doi: 10.1039/d3cc03960a.

Authors

Chen Li¹, Zhuo Chen¹, Xue-Yang Guo¹, Li-Rong Wen¹, Ming Li¹, Lin-Bao Zhang¹

Affiliation

¹ State Key Laboratory Base of Eco-Chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China. liming928@qust.edu.cn.

PMID: 37743839
DOI: 10.1039/d3cc03960a

Abstract

An electrooxidation direct difunctionalization of alkynes with sulfonyl hydrazides has been developed for the construction of sulfonyl alkenyl sulfates in the absence of metal catalysts and a stoichiometric amount of oxidants. Notably, it is the first example to verify that SO₄^2- ions can act as a nucleophilic reagent for the preparation of organosulfates.