Advanced degradation of refractory organic compounds in electroplating wastewater by an in-situ electro-catalytic biological coupling reactor: Removal performance, microbial community and possible mechanism

Abstract

A high-efficiency treatment system for advanced degradation of refractory organic compounds such as saccharin sodium (SS) and polyethylene glycol 6000 (PEG 6000) in electroplating wastewater was proposed, which coupled ion exchange, electrocatalysis, and microbial interactions through ion exchange particle electrode (IEPE) in a reactor, named in-situ electro-catalytic biological coupling reactor (i-SECBCR). A small-scale experimental test system was established and a feasibility investigation was conducted under the condition of 1.248 L/h continuous flow. The results revealed that (1) the i-SECBCR showed higher average removal rates of SS, PEG 6000, COD and NH₄⁺-N, i.e. 88.48 %, 41.26 %, 66.81 % and 51.61 %,which meant an increase by 5.04 %, 12.05 %, 0.46 %, and 34.50 %, respectively, compared with BAF; (2) the optimal current intensity (CI) of i-SECBCR for simultaneous removal of SS, PEG 6000, COD and NH₄⁺-N was 0.40 mA cm^-2; (3) Rhodobacter, Defluviimonas, unclassified_f__Microscillaceae, Pseudoxanthomonas, Novosphingobium, and unclassified_f__Xanthobacteraccae accounted for the main bacterial community in i-SECBCR; (4) the possible degradation mechanism was attributed mainly to the synergistic effect of ion exchange, electrocatalytic oxidation and biology. Therefore, the i-SECBCR was suitable to simultaneously advanced remove SS, PEG 6000, COD and NH₄⁺-N in electroplating wastewater.

Keywords: Advanced degradation; Current intensity; Electroplating wastewater; In-situ electrocatalytic biological coupling reactor; Refractory organic compounds.