Intercombination line frequencies in 171Yb validated with the clock transition

Appl Opt. 2023 May 20;62(15):3932-3940. doi: 10.1364/AO.488653.

Abstract

We have carried absolute frequency measurements of the (6s 2) 1 S 0-(6s6p) 3 P 1 transition in 171 Y b (intercombination line), where the spin-1/2 isotope yields two hyperfine lines. The measurements rely on sub-Doppler spectroscopy to yield a discriminator to which a 556 nm laser is locked. The frequency reference for the optical frequency measurements is a high-quality quartz oscillator steered to the GNSS time scale that is bridged with a frequency comb. The reference is validated to ∼3×10-12 by spectroscopy on the 1 S 0- 3 P 0 (clock) line in laser cooled and trapped 171 Y b atoms. From the hyperfine separation between the F=1/2 and F=3/2 levels of 3 P 1, we determine the hyperfine constant to be A(3 P 1)=3957833(28)k H z.