Upconversion Luminescence in Mononuclear Yb/Sm Co-crystal Assemblies at Room Temperature

Abstract

Metal-based upconversion luminescence transforming high-energy photons into low-energy photons is an attractive anti-Stokes shift process for fundamental research and promising applications. In this work, we developed the upconversion luminescence in co-crystal assemblies consisting of discrete mononuclear Yb and Sm complexes. The characteristic visible emissions of Sm³⁺ were observed under the excitation of absorption band of Yb³⁺ at 980 nm. A series of co-crystal assemblies were investigated based on mononuclear Yb and Sm complexes, and the strongest luminescence was obtained when the molar concentration between Yb³⁺ and Sm³⁺ is equivalent. The crystal structure was fully characterized by the single crystal X-ray diffraction and upconverting energy transfer mechanisms were verified as cooperative sensitization upconversion and energy transfer upconversion. This is the first example of Sm³⁺ -based upconverting luminescence in discrete lanthanide complexes which present as co-crystal assemblies at room temperature.

Keywords: Co-Crystal Assembly; Cooperative Sensitization Upconversion; Down-Shifting Luminescence; Lanthanide Complex; Molecular Upconversion.