Effect of alkaline pre-treatment on hydrolysis rate and methane production during anaerobic digestion of paunch solid waste

Abstract

Paunch is comprised of the partially digested feed contained in cattle or sheep and contributes 20-50% of organic waste produced at red meat processing facilities. Anaerobic digestion has been identified as a promising technology for paunch treatment, however treatment times can be long and when combined with the moderate degradability of paunch this results in high treatment costs that need to be improved. Pre-treatment was investigated as a strategy to improve AD of paunch, alkaline treatment (NaOH or KOH) was selected due to the high lignin content. A range of alkaline loadings (1-20 g 100gTS^-1) were tested with an equivalent hydroxide molar concentration of 9-250 mM [OH^-]. Alkaline pre-treatment improved both the hydrolysis rate and the overall degradability of paunch solid by up to 4.4 times and 60%, respectively. The enhanced hydrolysis rate and methane yield was correlated to changes in material composition during pre-treatment. While alkaline concentration was an important factor, there were no significant improvements at alkaline concentrations above 12 g 100gTS^-1 (150 mM [OH^-]).

Keywords: Alkaline pre-treatment; Anaerobic digestion; Lignocellulose biomass; Paunch; Red meat processing (RMP).