Developing new energy techniques that simultaneously integrate the fast rate capabilities of supercapacitors and high capacities of batteries represents an ultimate goal in the field of electrochemical energy storage. A new possibility arises with an emerging battery chemistry that relies on proton-ions as the ion-charge-carrier and benefits from the fast transportation kinetics. Proton-based battery chemistry starts with the recent discoveries of materials for proton redox reactions and leads to a renaissance of proton batteries. In this article, the historical developments of proton batteries are outlined and key aspects of battery chemistry are reviewed. First, the fundamental knowledge of proton-ions and their transportation characteristics is introduced; second, Faradaic electrodes for proton storage are categorized and highlighted in detail; then, reported electrolytes and different designs of proton batteries are summarized; last, perspectives of developments for proton batteries are proposed. It is hoped that this review will provide guidance on the rational designs of proton batteries and benefit future developments.
Keywords: electrochemical proton storage; energy storage; faradaic electrodes; proton batteries; pseudocapacitance.
© 2023 The Authors. Small Methods published by Wiley-VCH GmbH.