A novel sacrificial solvent method to synthesize self-supporting Co9S8/Ni3S2 heterostructure catalyst for efficient oxygen evolution reaction

Chang Gao; Linghui Kong; Lu Pan; Dongxv Li; Jianjian Lin

doi:10.1016/j.jcis.2023.08.186

A novel sacrificial solvent method to synthesize self-supporting Co₉S₈/Ni₃S₂ heterostructure catalyst for efficient oxygen evolution reaction

J Colloid Interface Sci. 2023 Dec 15;652(Pt B):1756-1763. doi: 10.1016/j.jcis.2023.08.186. Epub 2023 Aug 29.

Authors

Chang Gao¹, Linghui Kong¹, Lu Pan¹, Dongxv Li¹, Jianjian Lin²

Affiliations

¹ Key Laboratory of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, PR China.
² Key Laboratory of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, PR China. Electronic address: Jianjian_Lin@qust.edu.cn.

PMID: 37672978
DOI: 10.1016/j.jcis.2023.08.186

Abstract

Synthesizing catalysts for efficient oxygen evolution reaction (OER) with lower cost and simpler design is of significant importance to achieve sustainable hydrogen production. In this work, we propose a novel "sacrificial solvent method" for the first time. Dicobalt octacarbonyl (Co₂(CO)₈), dimethyl sulfoxide (DMSO), and Ni foam (NF) were used as the raw materials in the solvothermal process. DMSO played the role of both the sacrificial solvent and the sulfur source. Through the self-consumption of DMSO, we finally obtained the Co₉S₈/Ni₃S₂ heterostructure supported on the NF (Co₉S₈/Ni₃S₂@NF) in one step. The Co₉S₈/Ni₃S₂@NF catalyst exhibited excellent OER activity in alkaline environment, with an overpotential of only 264 mV at a current density of 20 mA cm^-2, a low Tafel slope of 68.28 mV dec^-1 and maintained its current density after 20 h of constant potential testing. This work introduces a new method for synthesizing metal sulfide catalysts using DMSO as a sacrificial solvent. It provides broader opportunities for the development of more efficient and sustainable catalysts for energy conversion and storage.

Keywords: Dimethyl sulfoxide; Electrocatalysis; Heterostructure; Oxygen evolution reaction; Sacrificial solvent method; Transition metal.