p-Type Functionalized Carbon Nanohorns and Nanotubes in Perovskite Solar Cells

Helena Uceta; Andrea Cabrera-Espinoza; Myriam Barrejón; José G Sánchez; Edgar Gutierrez-Fernandez; Ivet Kosta; Jaime Martín; Silvia Collavini; Eugenia Martínez-Ferrero; Fernando Langa; Juan Luis Delgado

doi:10.1021/acsami.3c07476

p-Type Functionalized Carbon Nanohorns and Nanotubes in Perovskite Solar Cells

ACS Appl Mater Interfaces. 2023 Sep 27;15(38):45212-45228. doi: 10.1021/acsami.3c07476. Epub 2023 Sep 6.

Affiliations

¹ Instituto de Nanociencia, Nanotecnología y Materiales Moleculares (INAMOL), Universidad de Castilla-La Mancha, Avenida Carlos III S/N, Toledo 45071, Spain.
² POLYMAT, University of the Basque Country UPV/EHU, Avenida Tolosa 72, Donostia/San Sebastián 20018, Spain.
³ Institute of Chemical Research of Catalonia-The Barcelona Institute of Science and Technology (ICIQ-BIST), Avinguda Països Catalans 16, Tarragona 43007, Spain.
⁴ CIDETEC, Basque Research and Technology Alliance (BRTA), Paseo Miramón 196, Donostia/San Sebastián 20014, Spain.
⁵ Ikerbasque, Basque Foundation for Science, Bilbao 48013, Spain.

Abstract

The incorporation of p-type functionalized carbon nanohorns (CNHs) in perovskite solar cells (PSCs) and their comparison with p-type functionalized single- and double-walled carbon nanotubes (SWCNTs and DWCNTs) are reported in this study for the first time. These p-type functionalized carbon nanomaterial (CNM) derivatives were successfully synthesized by [2 + 1] cycloaddition reaction with nitrenes formed from triphenylamine (TPA) and 9-phenyl carbazole (Cz)-based azides, yielding CNHs-TPA, CNHs-Cz, SWCNTs-Cz, SWCNTs-TPA, DWCNTs-TPA, and DWCNTs-Cz. These six novel CNMs were incorporated into the spiro-OMeTAD-based hole transport layer (HTL) to evaluate their impact on regular mesoporous PSCs. The photovoltaic results indicate that all p-type functionalized CNMs significantly improve the power conversion efficiency (PCE), mainly by enhancing the short-circuit current density (J_sc) and fill factor (FF). TPA-functionalized derivatives increased the PCE by 12-17% compared to the control device without CNMs, while Cz-functionalized derivatives resulted in a PCE increase of 4-8%. Devices prepared with p-type functionalized CNHs exhibited a slightly better PCE compared with those based on SWCNTs and DWCNTs derivatives. The increase in hole mobility of spiro-OMeTAD, additional p-type doping, better energy alignment with the perovskite layer, and enhanced morphology and contact interface play important roles in enhancing the performance of the device. Furthermore, the incorporation of p-type functionalized CNMs into the spiro-OMeTAD layer increased device stability by improving the hydrophobicity of the layer and enhancing the hole transport across the MAPI/spiro-OMeTAD interface. After 28 days under ambient conditions and darkness, TPA-functionalized CNMs maintained the performance of the device by over 90%, while Cz-functionalized CNMs preserved it between 75 and 85%.

Keywords: additives; carbon nanohorns (CNHs); carbon nanomaterials (CNMs); double-walled carbon nanotubes (DWCNTs); p-type doping; perovskite solar cells (PSCs); single-walled carbon nanotubes (SWCNTs); spiro-OMeTAD.