Hydrothermal carbonization (HTC) of dairy waste: effect of temperature and initial acidity on the composition and quality of solid and liquid products

Nidal Khalaf; Wenxuan Shi; Owen Fenton; Witold Kwapinski; J J Leahy

doi:10.12688/openreseurope.14863.2

Hydrothermal carbonization (HTC) of dairy waste: effect of temperature and initial acidity on the composition and quality of solid and liquid products

Open Res Eur. 2023 Sep 6:2:83. doi: 10.12688/openreseurope.14863.2. eCollection 2022.

Authors

Nidal Khalaf¹, Wenxuan Shi², Owen Fenton², Witold Kwapinski¹, J J Leahy¹

Affiliations

¹ Chemical and Environmental Science Department, University of Limerick, Limerick, Limerick, V94 T9PX, Ireland.
² Teagasc, Environmental Research Centre, Johnstown Castle, Co, Wexford, Y35 TC97, Ireland.

Abstract

Background: Hydrothermal carbonization (HTC) of dairy processing waste was performed to investigate the effect of temperature and initial pH on the yield and composition of the solid (hydrochar) and liquor produced. All hydrochars met the EU requirements of organo-mineral solid fertilizers defined in the Fertilizing Products Regulation in terms of phosphorus (P) and mineral content. Methods: Laboratory scale HTC was performed using pressurized reactors, and the products (solid and liquid) were collected, stored and analyzed for elemental composition and nutrient content using Inductively coupled plasma optical emission spectroscopy (ICP-OES), ultraviolet-visible spectrophotometry (UV-Vis) and other analytic techniques. Results: Maximum hydrochar yield (60.67%) was observed at T=180℃ and pH=2.25, whereas the maximum P-recovery was 80.38% at T=220℃ and pH=4.6. The heavy metal content of the hydrochars was mostly compliant with EU limitations, except for Ni at T=220℃ and pH=8.32. Meanwhile, further study of Chromium (Cr) species is essential to assess the fertilizer quality of the hydrochars. For the liquid product, the increase in temperature beyond 200℃, coupled with an increase in initial acidity (pH=2.25) drove P into the liquor. Simultaneously, increasing HTC temperature and acidity increased the concentration of NO ₃ ^- and NH ₄ ⁺ in the liquid products to a maximum of 278 and 148 mg/L, respectively, at T=180℃ and pH=4.6. Furthermore, no direct relation between final pH of liquor and NH ₄ ⁺ concentration was observed. Conclusions: HTC allows for the production of hydrochar as a potential fertilizer material that requires further processing. Adjusting HTC conditions enhanced P-recovery in the hydrochar, while retrieving higher nitrate concentrations in the liquid product. Optimizing HTC for the production of qualified hydrochars requires further treatment of Cr content, studying the availability of P in the products and enhancing the hydrochar yield for economic feasibility.

Keywords: Dairy Waste; HTC; Heavy Metals; Hydrochar; Phosphorus; STRUBIAS.

Grants and funding

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement number 814258.