A and B sites doped CaAl12O19: Phase component, energy band, color and photoluminescence tuning, color performance prediction and application for pigments

Yujia Jin; Shifa Wang; Xinmiao Yu; Maoyuan Li; Huajing Gao; Hua Yang; Leiming Fang; Yuanyuan Zhang; Jinjin Ding; Hao Liu; Xiangyu Chen; Mengjun Han; Angadi V Jagadeesha; Mohd Ubaidullah; Bidhan Pandit; Dengfeng Li

doi:10.1016/j.saa.2023.123254

A and B sites doped CaAl₁₂O₁₉: Phase component, energy band, color and photoluminescence tuning, color performance prediction and application for pigments

Spectrochim Acta A Mol Biomol Spectrosc. 2024 Jan 5:304:123254. doi: 10.1016/j.saa.2023.123254. Epub 2023 Aug 12.

Authors

Yujia Jin¹, Shifa Wang², Xinmiao Yu¹, Maoyuan Li¹, Huajing Gao¹, Hua Yang³, Leiming Fang⁴, Yuanyuan Zhang¹, Jinjin Ding¹, Hao Liu¹, Xiangyu Chen¹, Mengjun Han¹, Angadi V Jagadeesha⁵, Mohd Ubaidullah⁶, Bidhan Pandit⁷, Dengfeng Li⁸

Affiliations

¹ School of Electronic and Information Engineering, Chongqing Three Gorges University, Chongqing, Wanzhou 404000, China.
² School of Electronic and Information Engineering, Chongqing Three Gorges University, Chongqing, Wanzhou 404000, China. Electronic address: wangshifa2006@yeah.net.
³ School of Science, Lanzhou University of Technology, Lanzhou 730050, China.
⁴ Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Sichuan, Mianyang 621900, China. Electronic address: flmyaya2008@163.com.
⁵ Department of Physics, P.C. Jabin Science College, Hubballi 580031, Karnataka, India.
⁶ Department of Chemistry, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia. Electronic address: mtayyab@ksu.edu.sa.
⁷ Department of Materials Science and Engineering and Chemical Engineering, Universidad Carlos III de Madrid, Avenida de la Universidad 30, 28911 Leganés, Madrid, Spain.
⁸ School of Science, Chongqing University of Posts and Telecommunications, Nan'an District, 400065 Chongqing, China. Electronic address: lidf@cqupt.edu.cn.

PMID: 37633097
DOI: 10.1016/j.saa.2023.123254

Abstract

The polyacrylamide gel method was used to fabricate the Ca_1-xCo_xAl₁₂O₁₉, Ca_1-xNi_xAl₁₂O₁₉, CaAl_12-xIn_xO₁₉ and CaAl_12-xW_xO₁₉ (x = 0-0.5) pigments. The phase compositions, energy bands, color and photoluminescence properties of the pigments can be controlled by adjusting the type and content of doping ions. The color of CaAl₁₂O₁₉ changed from white to blue with the Co²⁺ ion doping, from white to gray green with the Ni²⁺ ion doping, and from white to bright white with the In³⁺ and W⁶⁺ ions doping. The genetic algorithm optimized back propagation neural network can predict the color properties of CaAl₁₂O₁₉ based pigments. The application of the pigments shows that they can be used in painting, coating and other fields. The Co²⁺ and Ni²⁺ doped CaAl₁₂O₁₉ exhibits high blue emission, while In³⁺ and W⁶⁺ doped CaAl₁₂O₁₉ shows strong green emission and the luminescence is highly dependent on the type and content of dopant ion, phase composition and energy transfer.

Keywords: CaAl(12)O(19); Energy transfer; Genetic algorithm; Neural network; Polyacrylamide gel method.