Phase-Field Study of Exchange Coupling in Co-Pt Nonstandard Nanochessboards

Materials (Basel). 2023 Aug 18;16(16):5689. doi: 10.3390/ma16165689.

Abstract

The Co-Pt binary system can form a two-phase nanochessboard structure comprising regularly aligned nanorods of magnetically hard tetragonal L10 phase and magnetically soft cubic L12 phase. This Co-Pt nanochessboard, being an exchange-coupled magnetic nanocomposite, exhibits a strong effect on magnetic domains and coercivity. While the ideal nanochessboard structure has tiles with equal edge lengths (a = b), the non-ideal or nonstandard nanochessboard structure has tiles with unequal edge lengths (a ≠ b). In this study, we employed phase-field modeling and computer simulation to systematically investigate the exchange coupling effect on magnetic properties in nonstandard nanochessboards. The simulations reveal that coercivity is dependent on the length scale, with magnetic hardening occurring below the critical exchange length, followed by magnetic softening above the critical exchange length, similar to the standard nanochessboards. Moreover, the presence of unequal edge lengths induces an anisotropic exchange coupling and shifts the coercivity peak with the length scale.

Keywords: domain mechanism; exchange coupling; nanochessboard; phase-field modeling.