Carbon dioxide-assisted thermochemical conversion of magnetically harvested harmful algae into syngas and metal biochar

Abstract

With rising of harmful algae blooming and toxin exposure, practical utilization of harmful algae has been developed. This work aimed to magnetically harvest Microcystis aeruginosa (MA) using iron oxides and investigate the feasibility of algae/iron oxides mixture as feedstock in pyrolytic platform to produce syngas and metal biochar. Carbon dioxide (CO₂) was used as a feeding gas to enhance the production efficiency of syngas and also functioned pH controller for better MA harvesting and toxin removal. CO₂ support brought multiple benefits: magnetite (Fe₃O₄) and maghemite (γ-Fe₂O₃) recovered MA in a relatively short period of time (∼1 min), the recovered biomass generated 34-fold increased carbon monoxide, and metal biochar adsorbed higher amount of toxin from MA (2.8-fold). Pyrolytic utilization of harmful algae supported by CO₂ and iron oxides could be one of promising techniques for evolution of metal biochar to remove toxin, while efficiently recover biomass and enhance syngas production.

Keywords: Carbon dioxide-assisted co-pyrolysis; Metal-biochar; Microcystin; Microcystis aeruginosa; Syngas generation.