The model and mechanism of adsorptive technologies for wastewater containing fluoride: A review

Abstract

With the continuous development of society, industrialization, and human activities have been producing more and more pollutants. Fluoride discharge is one of the main causes of water pollution. This review summarizes various commonly used and effective fluoride removal technologies, including ion exchange technology, electrochemical technology, coagulation technology, membrane treatment, and adsorption technology, and points out the outstanding advantages of adsorption technology. Various commonly used fluoride removal techniques as well as typical adsorbent materials have been discussed in published papers, however, the relationship between different adsorbent materials and adsorption models has rarely been explored, therefore, this paper categorizes and summarizes the various models involved in static adsorption, dynamic adsorption, and electrosorption fluoride removal processes, such as pseudo-first-order and pseudo-second-order kinetic models, Langmuir and Freundlich isotherm models, Thomas and Clark dynamic adsorption models, including the mathematical equations of the corresponding models and the significance of the models are also comprehensively summarized. Furthermore, this comprehensive discussion delves into the fundamental adsorption mechanisms, quantification of maximum adsorption capacity, evaluation of resistance to anion interference, and assessment of adsorption regeneration performance exhibited by diverse adsorption materials. The selection of the best adsorption model not only predicts the adsorption performance of the adsorbent but also provides a better description and understanding of the details of each part of the adsorption process, which facilitates the adjustment of experimental conditions to optimize the adsorption process. This review may provide some guidance for the development of more cost-effective adsorbent materials and adsorption processes in the future.

Keywords: Adsorption mechanism; Adsorption model; Fluoride; Wastewater.