Polyamic acid (PAA) was synthesized using the diamine monomer N,N'-[2,2'-bis(trifluoromethyl)-4,4'-biphenylene]bis(4-aminobenzamide) and dianhydride monomer 4,4'-oxydiphthalic anhydride. Colorless and transparent poly(amide imide) (CPAI) hybrid films were prepared via multi-step thermal imidization of PAA in which various contents of nano-filler were dispersed. The CPAI hybrid films were prepared by dispersing organoclay STN, which was obtained by organically modifying hectorite, in CPAI by solution intercalation with various contents ranging from 1 to 7 wt%. The thermomechanical properties, morphologies, and optical transparencies of the obtained CPAI hybrid films were investigated based on the dispersed STN content, and the results were compared. Some of the clay in the CPAI hybrid film were agglomerated, which was observed using a transmission electron microscope; however, most clays were well-dispersed, with a nano-size of less than 10 nm. The best thermomechanical properties of the CPAI hybrid film were exhibited with an STN content of 3 wt%, but these properties decreased above the critical content. The coefficients of thermal expansion of all the hybrid films were below 20 ppm per °C regardless of the amount of STN, and the yellow index was 1-2 even when the STN content increased to 7 wt%.
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