This study investigated the effect of overpressure on the deep shale pore system in the Wufeng-Longmaxi Formation (WLF), a well-established shale gas reservoir in the southern Sichuan Basin, China. The Y1 well was drilled to explore deeper overpressured sections of the basin. Organic geochemistry, mineralogy analysis, field emission scanning electron microscopy (FE-SEM), and gas physisorption experiments were conducted to analyze the pore system. Results showed that despite strong compaction, deep organic-rich shale retained large pores. Compared to shallow shale, deep shale had a larger organic porosity with a smaller average pore size, although some pore sizes exceeded those in shallow shale. Nitrogen (N2) adsorption indicated that the abundance of organic matter (OM) affected mesoporous volume and specific surface area (SSA), while carbon dioxide (CO2) adsorption experiments suggested that micropores were not influenced by OM abundance. Comparing calculated pore SSA and volume via gas adsorption of shallower and deep shale samples revealed that, under similar OM abundance, pore SSA was nearly identical, but deep shale had a larger pore volume than shallow shale. The preservation of pores, particularly in deep shale, is attributed to overpressure, which protects against collapse; additionally, generated shale gas during thermal evolution of OM serves as pore support.
© 2023 The Authors. Published by American Chemical Society.