Characteristics of Components and Density of Rigid Nanoclay-Filled Medium-Density Polyurethane Foams Produced in a Sealed Mould

Polymers (Basel). 2023 Jul 28;15(15):3228. doi: 10.3390/polym15153228.

Abstract

The characteristics of rigid, nanoclay-filled, medium-density NEOpolyol-380 polyurethane foams components can be estimated when two conditions are met: (1) the foam blocks are produced in a sealed mould; and (2) the mass of the reacting mixture is kept constant. It was shown that, with an increase in filler concentration, the total mass of the filled polymeric network stays constant, but the total volume reduces; the higher the ratio of density of the exfoliated nanoclay platelets and polymer, the higher the volume reduction of the polymeric network. Experimental data of polyurethane foam block mass were acquired at concentrations η = 0%, 0.25%, 0.5%, 1%, 2%, 3% and 5% from the mass of a filled reacting mixture. Foam-density dependence in the uniform zone and in the side-sections of the produced blocks on the: (1) mass of the blocks; and (2) the concentration of the filler was analysed. The study demonstrated that the correlation of the specimens' density with the foam block mass is much higher than that of the filler concentration.

Keywords: composite; concentration; filler; mass; medium density; nanoclay; polyurethane foams; sealed mould; volume.