Demonstrating removal credits for contaminants of emerging concern in recycled water through a reverse osmosis barrier-A predictive framework

Abstract

The performance of individual reverse osmosis (RO) systems varies significantly with different contaminants of emerging concern (CECs). As such, log reduction values (LRVs) of the concentration of these chemicals cannot be arbitrarily credited in water treatment and water recycling. This study looks to present an approach to the management of chemical risks by providing a systematic validation of RO barrier performance with respect to LRV credits for various classes of CECs. In this work, a one-off sampling campaign across five treatment barriers (strainer filtration, ultrafiltration, RO, ion exchange, chlorination) of a full-scale water recycling plant was conducted, followed by a systematic sampling campaign for a period of six weeks across just the RO barrier. The CECs screening methodology used GC-MS for quantification of 948 trace organic chemicals along with specific 44 per- and polyfluoroalkyl substances (PFAS) screening using LC-MS/MS to demonstrate the removal credits of the RO barrier to a wide spectrum of CECs. The work was used to validate an LRV barrier credit framework so as to predict the performance of a polyamide RO membrane for removal of a range of chemical classes, under typical operational conditions. Conductivity was validated as an efficient surrogate for membrane integrity and RO performance, along with specified operational conditions associated with permeate flux and recovery rate. A bioassay method (photobacterium test) showed good potential to be used as a quick measure to indicate the general toxicity of a sample caused by chemical contamination, because of its high detection sensitivity and time and cost efficiency.

Keywords: Contaminants of emerging concern; Removal credit; Reverse osmosis; Treatment validation; Water recycling.