SiP-heterocycles derived from a bulky phosphanylsilylene

Chenfeng Wang; Ming-Der Su; Zijie Fang; Jiahao Zhou; Haoqi Zhang; Xiaodi Li; Darui Zuo; Zheng-Feng Zhang; Yan Li

doi:10.1039/d3cc02512h

SiP-heterocycles derived from a bulky phosphanylsilylene

Chem Commun (Camb). 2023 Aug 22;59(68):10275-10278. doi: 10.1039/d3cc02512h.

Authors

Chenfeng Wang¹, Ming-Der Su^{2

3}, Zijie Fang¹, Jiahao Zhou¹, Haoqi Zhang¹, Xiaodi Li¹, Darui Zuo¹, Zheng-Feng Zhang², Yan Li^{1

4}

Affiliations

¹ College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Hangzhou, 311121, China. yli@hznu.edu.cn.
² Department of Applied Chemistry, National Chiayi University, Chiayi, 60004, Taiwan.
³ Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, Kaohsiung 80708, Taiwan.
⁴ Key Laboratory of Silicone Materials Technology of Zhejiang Province, Hangzhou Normal University, Hangzhou 311121, PR China.

PMID: 37539464
DOI: 10.1039/d3cc02512h

Abstract

Bis(1-adamantyl)phosphanylsilylene 1 was reacted with ArCCR (Ar = Ph, 4-iPr-C₆H₄, 3-F-C₆H₄; R = H, Ph) at 80 °C under microwave irradiation to afford fluorescence-active SiP-heterocycles 3a-d, which may undergo unique isomerizations starting from silirene intermediates. Moreover, the treatment of 1 with AdCP furnished a heavy congener of cyclopentadiene (4), whose formation involves cleavage of the Si(II)-P bond that is rarely observed in silylene chemistry.