Natural iron-aluminosilicate as potential solid precursor for supplementary cementitious materials: A comparative study with other aluminosilicates

Joelle Nadia Nouping Fekoua; Paul Venyite; Seunkole Bila; Elie Kamseu; Gouet Bebga; Myriam Hanuskova; Giovanni Dal Poggetto; Sylvie Rossignol; Cristina Leonelli

doi:10.1016/j.heliyon.2023.e17750

Natural iron-aluminosilicate as potential solid precursor for supplementary cementitious materials: A comparative study with other aluminosilicates

Heliyon. 2023 Jul 5;9(7):e17750. doi: 10.1016/j.heliyon.2023.e17750. eCollection 2023 Jul.

Authors

Joelle Nadia Nouping Fekoua^{1

2

3

4}, Paul Venyite^{1

2}, Seunkole Bila⁵, Elie Kamseu^{2

6}, Gouet Bebga⁴, Myriam Hanuskova⁶, Giovanni Dal Poggetto⁶, Sylvie Rossignol³, Cristina Leonelli⁶

Affiliations

¹ Laboratory of Applied Inorganic Chemistry, University of Yaounde I, P.O. Box 812, Yaoundé, Cameroon.
² Laboratory of Materials, Local Materials Promotion Authority, MINRESI/MIPROMALO, P.O. Box 2396, Yaoundé, Cameroon.
³ UMR CNRS 7315, CEC, Institut de Recherche sur les Céramiques (IRCER), Université de Limoges, 12 Rue Atlantis, Limoges, France.
⁴ Computational Chemistry Laboratory, High Teacher Training College, University of Yaound'e I, P.O. Box 47, Yaounde, Cameroon.
⁵ Laboratory of Mechanical and Civil Engineering- Polytechnic National High School of Yaounde, Universitu of YaoundeI, P.O.Box 8390, Yaounde, Cameroon.
⁶ Department of Engineering "Enzo Ferrari", University of Modena and Reggio Emilia, ViaP. Vicarelli 10, 41125, Modena, Italy.

Abstract

The objective of this study was to investigate the impact of the geographic and climatic conditions on laterites properties and on geopolymerization based-laterite. Four different laterite deposits in the four geographical zones of Cameroon were studied. This included the center, north, south and west corners of Cameroon, having chemical composition of SiO₂ + Al₂O₃ + Fe₂O₃ = 88.94, 87.6, 89.13 and 78.97%, respectively. The center and south laterites from the black forest, with high pluviometry and relative humidity, show significant amounts of Fe₂O₃. While the west laterite from grass field - mountainous areas and the north-laterite from plain arid and semi-arid climate still show lower iron concentrations. The IR absorption bands of the different laterites appear between 1007 and 1047 cm^-1; characteristic bands of aluminosilicate. The BET (Brunauer-Emmett-Teller) Specific surface area values are comprised in the range of [21.9, 24.1 m²/g] for non-calcined laterite and between [45.6 and 123.5 m²/g] for laterites calcined at 550 °C and 575 °C. The main particle size values are 5.71, 6.37, 7.43 and 8.45 μm for center-laterite, west-laterite, north laterite and south-laterite, respectively. Although, they differ in the degree of laterization, all the laterites present almost total conversion to geopolymers, due to the presence of amorphous kaolinite and reactive goethite. However, the iron content has significant impact on the globular microstructure. The particle size of laterites, their high values of BET surface area and their significant reactivity make them promising substitutes to metakaolin and other supplementary cementitious materials.

Keywords: Climate-conditions; Géopolymer; Laterite; Reactivity; Supplementary cementitious materials.