Directional Crystallization of Conjugated Molecules during Coating Processes

Molecules. 2023 Jul 13;28(14):5371. doi: 10.3390/molecules28145371.

Abstract

The coating of organic molecules from the solution phase can result in directional crystal growth under certain conditions, even on a smooth isotropic surface and without the need of any kind of graphoexpitaxial preparation of the substrate. Based on reviewing the results from a variety of coating techniques and coating parameters, we identified that it is crucial for the coating speed to match the growth speed of the fastest growing crystal plane to achieve a high degree of directional crystallization.

Keywords: coating techniques; conjugated molecules; crystallization.