In recent years, excessive exploitation and rapid population growth have posed numerous challenges. The climate crisis is deepening because of the unabated use of fossil fuels and the ascendance of greenhouse gas levels, so there is still an urgent need to seek different clean energy sources and electricity generating methods with the purpose of adjusting energy structures and solving environmental problems. In the ubiquitous hydrologic cycle, at least 60 petawatts (1015 W) energy can be supplied, but little of it has yet been utilized. Nowadays, hydrovoltaic intelligence has emerged and exhibited an ecofriendly concept of electricity generation compared with traditional methods with the rise of nanoscience and nanomaterials. Hence, it provides the prospect of upgrading the mode of water energy use, constructing a renewable energy industry, and alleviating environmental issues. In this review, starting by introducing different types of hydrovoltaic effect mechanisms─energy harvesting based on drawing potential of liquids; energy harvesting based on water evaporation, and energy harvesting based on moisture adsorption─we summarize the fabrication processes, material classifications, intelligent applications, and representative advances in detail. Moreover, the future development trends of hydrovoltaic intelligence and the challenges for improvement in electrical output are further discussed.
Keywords: challenge; development; electricity generation; hydrovoltaic intelligence; liquid−solid interface; moisture−solid interface; nanomaterial; sensing.