In nature, some organisms have the ability to camouflage to adapt to environmental changes; they blend with the environment by changing their skin colors. Such a phenomenon is of great significance for the research of adaptive camouflage materials. In this study, we propose a novel design scheme for the study of angle-independent photonic materials and successfully prepare an electrically tunable multi-color display angle-independent inverse opal photonic gel (IOPG). After photopolymerization of hydroxyethyl methacrylate with ionizable monomer acrylic acid (AA) in a long-range disordered opal template and etching, the angle-independent inverse opal photonic gel is obtained, presenting a single structural color. The electrically responsive color changes can be achieved at different angles. The color of the disordered AA-IOPG changes from green to blue-green when applying +4 V bias voltage and from green to orange when applying -4 V bias voltage. The electrochromism of the disordered AA-IOPG is mainly due to the local pH change caused by water electrolysis under bias voltage, which leads to a change of the swelling ratio. The disordered AA-IOPG shows high color tunability and durability through repeated opposite bias voltage tests, indicating that it is a promising conductive photonic material.
Keywords: electro-responsive; hydrogel; inverse opal; photonic crystal; structural color.