Metal-mediated tunability of MOF-based optical modulators

Nikita K Kulachenkov; Bogdan Orlioglo; Eugene S Vasilyev; Svyatoslav A Povarov; Alexander M Agafontsev; Semyon Bachinin; Sergei Shipilovskikh; Artem Lunev; Denis G Samsonenko; Vladimir P Fedin; Konstantin A Kovalenko; Valentin A Milichko

doi:10.1039/d3cc02180g

Metal-mediated tunability of MOF-based optical modulators

Chem Commun (Camb). 2023 Aug 15;59(66):9964-9967. doi: 10.1039/d3cc02180g.

Affiliations

¹ School of Physics and Engineering, ITMO University, St. Petersburg, 197101, Russia.
² Chemical Science Program, KAUST Catalysis Center, Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Saudi Arabia.
³ Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9 Acad. Lavrentiev Ave., Novosibirsk 630090, Russia.
⁴ Novosibirsk State University, 2 Pirogova St., Novosibirsk 630090, Russia.
⁵ Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Ave., Novosibirsk 630090, Russia. k.a.kovalenko@niic.nsc.ru.
⁶ Universit de Lorraine, UMR CNRS 7198, Nancy 54011, France. valentin.milichko@univ-lorraine.fr.

PMID: 37501597
DOI: 10.1039/d3cc02180g

Abstract

We report on the design of 1D MOFs based on a nopinane-annelated organic ligand and Co(II) or Ni(II), the variation of which allows tuning the optical modulation bandwidth. Structural and time-resolved analysis revealed the optical modulation mechanism, the rates and its endurance, thereby enriching the list of sustainable MOFs for tunable optical modulators.