Perspectives on a Few Puzzles in Phase Transformations: When Should the Farthest Reach the Earliest?

Langmuir. 2023 Aug 8;39(31):10715-10723. doi: 10.1021/acs.langmuir.3c00668. Epub 2023 Jul 27.

Abstract

We briefly review the facts concerning two important aspects of phase transitions, namely, critical and coarsening phenomena. A discussion of the universal features, highlighting the current challenges, is provided. Following this, we elaborate on a topic of much recent interest, viz., the Mpemba effect, a puzzle that found mention even in the works of Aristotle. After a description of the debated case of faster freezing of a hotter sample of liquid water, into ice, than a colder one, when quenched to the same subzero temperature, we discuss more modern interest. There one asks, should a hotter body of a material equilibrate faster than a colder one when quenched to a common lower temperature? Within this broad scenario, we focus on magnetic systems. A surprising observation of the effect during the para- to ferromagnetic transition, in a simple model system, viz., the nearest-neighbor Ising model, without any built-in frustration, is described. Some associated future directions are pointed out. A discussion is provided by considering the effect as a kinetic outcome in the background of critical phenomena. A picture is drawn by putting emphasis on the role of spatial correlations in the initial configurations alongside discussing the importance of frustration and metastability in evolution from one state to another. In connection with dynamical freezing, concerning metastability, we have introduced the complex Ginzburg-Landau equation that has relevance in phase transitions, chemical oscillations, and elsewhere. For this model and a few other cases also, we have described how a lack of order or correlation in certain parameters can lead to quicker evolution.

Publication types

  • Review