Two-Dimensional Carbon Graphdiyne: Advances in Fundamental and Application Research

Xuchen Zheng; Siao Chen; Jinze Li; Han Wu; Chao Zhang; Danyan Zhang; Xi Chen; Yang Gao; Feng He; Lan Hui; Huibiao Liu; Tonggang Jiu; Ning Wang; Guoxing Li; Jialiang Xu; Yurui Xue; Changshui Huang; Chunying Chen; Yanbing Guo; Tong-Bu Lu; Dan Wang; Lanqun Mao; Jin Zhang; Yue Zhang; Lifeng Chi; Wanlin Guo; Xian-He Bu; Hongjie Zhang; Liming Dai; Yuliang Zhao; Yuliang Li

doi:10.1021/acsnano.3c03849

Two-Dimensional Carbon Graphdiyne: Advances in Fundamental and Application Research

ACS Nano. 2023 Aug 8;17(15):14309-14346. doi: 10.1021/acsnano.3c03849. Epub 2023 Jul 20.

Authors

Xuchen Zheng^{1

2}, Siao Chen^{1

2}, Jinze Li^{1

2}, Han Wu^{1

2}, Chao Zhang^{1

2}, Danyan Zhang^{1

2}, Xi Chen^{1

2}, Yang Gao¹, Feng He¹, Lan Hui¹, Huibiao Liu^{1

2}, Tonggang Jiu³, Ning Wang³, Guoxing Li³, Jialiang Xu⁴, Yurui Xue^{1

3}, Changshui Huang¹, Chunying Chen⁵, Yanbing Guo⁶, Tong-Bu Lu⁷, Dan Wang⁸, Lanqun Mao⁹, Jin Zhang¹⁰, Yue Zhang¹¹, Lifeng Chi¹², Wanlin Guo¹³, Xian-He Bu⁴, Hongjie Zhang¹⁴, Liming Dai¹⁵, Yuliang Zhao^{5

2}, Yuliang Li^{1

3

2}

Affiliations

¹ CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China.
² School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, P. R. China.
³ Shandong Provincial Key Laboratory for Science of Material Creation and Energy Conversion, Science Center for Material Creation and Energy Conversion, Institute of Frontier and Interdisciplinary, Shandong University, Qingdao 266237, P. R. China.
⁴ School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin 300350, P. R. China.
⁵ CAS Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety and CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology of China, Beijing 100190, P. R. China.
⁶ Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, Institute of Environmental and Applied Chemistry, College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China.
⁷ MOE International Joint Laboratory of Materials Microstructure, Institute for New Energy Materials and Low Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300350, P. R. China.
⁸ Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China.
⁹ College of Chemistry, Beijing Normal University, Beijing 100875, P. R. China.
¹⁰ Center for Nanochemistry, Beijing Science and Engineering Center for Nanocarbons, Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China.
¹¹ Academy for Advanced Interdisciplinary Science and Technology, Beijing Advanced Innovation Center for Materials Genome Engineering and Beijing Key Laboratory for Advanced Energy Materials and Technologies, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China.
¹² Institute of Functional Nano and Soft Materials, Soochow University, Soochow 1215031, P. R. China.
¹³ Key Laboratory for Intelligent Nano Materials and Devices of the Ministry of Education, State Key Laboratory of Mechanics and Control for Aerospace Structures, and Institute for Frontier Science, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China.
¹⁴ Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China.
¹⁵ Australian Carbon Materials Centre (A-CMC), School of Chemical Engineering, University of New South Wales, Sydney, New South Wales 2052, Australia.

PMID: 37471703
DOI: 10.1021/acsnano.3c03849

Abstract

Graphdiyne (GDY), a rising star of carbon allotropes, features a two-dimensional all-carbon network with the cohybridization of sp and sp² carbon atoms and represents a trend and research direction in the development of carbon materials. The sp/sp²-hybridized structure of GDY endows it with numerous advantages and advancements in controlled growth, assembly, and performance tuning, and many studies have shown that GDY has been a key material for innovation and development in the fields of catalysis, energy, photoelectric conversion, mode conversion and transformation of electronic devices, detectors, life sciences, etc. In the past ten years, the fundamental scientific issues related to GDY have been understood, showing differences from traditional carbon materials in controlled growth, chemical and physical properties and mechanisms, and attracting extensive attention from many scientists. GDY has gradually developed into one of the frontiers of chemistry and materials science, and has entered the rapid development period, producing large numbers of fundamental and applied research achievements in the fundamental and applied research of carbon materials. For the exploration of frontier scientific concepts and phenomena in carbon science research, there is great potential to promote progress in the fields of energy, catalysis, intelligent information, optoelectronics, and life sciences. In this review, the growth, self-assembly method, aggregation structure, chemical modification, and doping of GDY are shown, and the theoretical calculation and simulation and fundamental properties of GDY are also fully introduced. In particular, the applications of GDY and its formed aggregates in catalysis, energy storage, photoelectronic, biomedicine, environmental science, life science, detectors, and material separation are introduced.

Keywords: atomic catalysis; controlled growth; energy conversion; graphdiyne; intelligent device; life science; material separation; two-dimensional carbon materials.

Publication types

Review