Dihydroxyacetone production by glycerol oxidation under moderate condition using Pt loaded on La1- xBixOF solids

Naoyoshi Nunotani; Masanari Takashima; Yeon-Bin Choi; Yuta Uetake; Hidehiro Sakurai; Nobuhito Imanaka

doi:10.1039/d3cc01734f

Dihydroxyacetone production by glycerol oxidation under moderate condition using Pt loaded on La_{1- x}Bi_xOF solids

Chem Commun (Camb). 2023 Aug 1;59(62):9533-9536. doi: 10.1039/d3cc01734f.

Authors

Naoyoshi Nunotani¹, Masanari Takashima¹, Yeon-Bin Choi¹, Yuta Uetake^{1

2}, Hidehiro Sakurai^{1

2}, Nobuhito Imanaka¹

Affiliations

¹ Department of Applied Chemistry, Faculty of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan. imanaka@chem.eng.osaka-u.ac.jp.
² Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.

PMID: 37458093
DOI: 10.1039/d3cc01734f

Abstract

Pt/La_1-xBi_xOF/SBA-16 (SBA-16: Santa Barbara Amorphous no. 16) catalysts were prepared to produce dihydroxyacetone (DHA) from glycerol under moderate conditions. By using 7 wt% Pt/16 wt% La_0.95Bi_0.05OF/SBA-16, the DHA yield reached up to 78.4% (glycerol conversion: 100%) after reacting for 6 h at 30 °C in an atmospheric open-air system.