Flammability of Thick but Thermally Thin Materials including Bio-Based Materials

Molecules. 2023 Jul 3;28(13):5175. doi: 10.3390/molecules28135175.

Abstract

The fire reaction of various types of flammable lightweight materials is investigated using a cone calorimeter. The influences of parameters such as sample density, sample mass, effective heat of combustion and heat flux on the mass loss after exposition are discussed. Interpretations of the hemp fibers' tests results lead us to propose a phenomenological model able to calculate the peak of heat release rate (pHRR) of such thermally thin materials, with or without flame retardant. A database gathering the whole results of tests performed on a large set of materials including fibers, bio-resources panels, bio-based concretes and fabrics is used to validate the proposed model. Interestingly, the model is found to be relevant also for denser wood specimens. The model is based on the distinction of the contributions of the exposed top layer and the deeper layer to the combustion. Indeed, in such materials, the heat conduction is limited (either by the intrinsic properties of the material or by the formation of an insulating char) and therefore the pHRR only depends on a limited volume of materials directly absorbing the heat flux from the radiant cone. Accuracy and limitations of the model are discussed.

Keywords: bio-resources; cone calorimeter; fire behavior; hemp fibers; insulating materials; thermally thin materials; wood.

MeSH terms

  • Databases, Factual
  • Fires*
  • Flame Retardants*
  • Hot Temperature
  • Textiles

Substances

  • Flame Retardants

Grants and funding

This work was performed in the frame of French INNOFIB ADEME project, as part of the GRAINE 2019 project “INNOFIB” n°2103D0018-A. The project deals with the development of alternative fire-retardant treatment to conventional boric acid and ammonium salts solutions in order to limit the energy, sanitary and environmental impacts of the treatment, while optimizing the technical performance.