Tracking the Progression of the Simulated Bronze Disease-A Laboratory X-ray Microtomography Study

Molecules. 2023 Jun 23;28(13):4933. doi: 10.3390/molecules28134933.

Abstract

The internal three-dimensional characteristics of X-ray microtomography (micro-CT) has great application potential in the field of bronze corrosion. This work presents a method of simulating bronze disease based on an in situ micro-CT image to study the characteristics of the oxidative hydrolysis reactions of copper(I) chloride and copper(II) chloride dihydrate. A series of high-resolution reconstruction images were obtained by carrying out micro-CT at three key points throughout the experiment. We found that the reactions of copper(I) chloride and copper(II) chloride dihydrate showed different characteristics at different stages of the simulation in the micro-CT view. The method proposed in this work specifically simulated one single type of bronze corrosion and characterized the evolution characteristics of simulated bronze disease. It provides a new perspective to investigate bronze disease and can help improve the subsequent use of micro-CT to distinguish real bronze corrosions.

Keywords: bronze disease; in situ X-ray microtomography image; metal corrosion; simulation experiment.

MeSH terms

  • Chlorides
  • Copper*
  • Halogens*
  • X-Ray Microtomography / methods

Substances

  • cuprous chloride
  • cupric chloride
  • Copper
  • Halogens
  • Chlorides

Grants and funding

This research was funded by National Key Research and Development Project of China, grant number 2020YFC1522002.