Complete Desorption of Hybrid Nanoclays Composed of Hydrotalcite and Disperse Dye

Int J Mol Sci. 2023 Jun 30;24(13):10950. doi: 10.3390/ijms241310950.

Abstract

Clays are considered great nanoadsorbents for many materials, including textile dyes. The use of these materials for cleaning textile wastewater is well known; however, it is not at all common to find applications for the hybrid materials formed from the clay and dye. In this work, a dye-loaded clay material was used to make new dye baths and colour a polyester textile substrate. The same hybrid could be used several times as it did not use all the adsorbed dye in a single dyeing. The hybrid obtained from hydrotalcite (nanoclay) and the dispersed red 1 dye was analysed by measuring the colour obtained, carrying out an X-ray diffraction analysis that provided information after each desorption-dyeing process, and using infrared spectroscopy to analyse the specific bands of each characteristic group. Both analyses showed that the amount of dye present in the hybrid decreases. Thermogravimetry (TGA), surface area and porosity measurements (BET), and X-ray photoelectron spectroscopy (XPS) tests were conducted. Chemical stability was assessed by subjecting the hybrid to the actions of different reagents. In addition, colour fastness tests were carried out after dyeing and washing the polyester test tubes to check for the correct fixing of the dye to the fibre. These fastness results showed that the dyeing was carried out correctly and as if it was a conventional dyeing process.

Keywords: disperse dye recovery; dye adsorption; fastness colour dyeing clay; hydrotalcite; nanoclay dyeing; removal of dyes.

MeSH terms

  • Clay
  • Coloring Agents* / chemistry
  • Polyesters
  • Textiles*

Substances

  • Coloring Agents
  • Clay
  • hydrotalcite
  • Polyesters

Grants and funding

To the vice-rectorate for research of the UPV for Funding for open access charge: CRUE-Universitat Politècnica de València.