Li3Bi/Li2O layer with uniform built-in electric field distribution for dendrite free lithium metal batteries

Fei Zhu; Zekai Zhang; Jie Gu; Jinting Xu; Sukum Eitssayeam; Qunjie Xu; PengHui Shi; YuLin Min

doi:10.1016/j.jcis.2023.06.107

Li₃Bi/Li₂O layer with uniform built-in electric field distribution for dendrite free lithium metal batteries

J Colloid Interface Sci. 2023 Nov 15;650(Pt A):622-635. doi: 10.1016/j.jcis.2023.06.107. Epub 2023 Jun 17.

Authors

Fei Zhu¹, Zekai Zhang², Jie Gu³, Jinting Xu⁴, Sukum Eitssayeam⁵, Qunjie Xu¹, PengHui Shi¹, YuLin Min⁶

Affiliations

¹ Shanghai Key Laboratory of Materials Protection and Advanced Materials Electric Power, Shanghai Engineering Research Center of Energy-Saving in Heat Exchange Systems, Shanghai University of Electric Power, Shanghai 200090, China.
² School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, 200237, China.
³ China-UK Low Carbon College, Shanghai Jiao Tong University, Lingang, Shanghai 201306, China.
⁴ Shanghai Key Laboratory of Materials Protection and Advanced Materials Electric Power, Shanghai Engineering Research Center of Energy-Saving in Heat Exchange Systems, Shanghai University of Electric Power, Shanghai 200090, China. Electronic address: xujinting011291@shiep.edu.cn.
⁵ Physics and Materials science Department, Faculty of Science, Chiang Mai University, 239 Huay Kaew Road, Muang District, Chiang Mai 50200, Thailand.
⁶ Shanghai Key Laboratory of Materials Protection and Advanced Materials Electric Power, Shanghai Engineering Research Center of Energy-Saving in Heat Exchange Systems, Shanghai University of Electric Power, Shanghai 200090, China; Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China. Electronic address: minyulin@shiep.edu.cn.

PMID: 37437442
DOI: 10.1016/j.jcis.2023.06.107

Abstract

Lithium metal batteries have garnered significant attention as a promising energy storage technology, offering high energy density and potential applications across various industries. However, the formation of lithium dendrites during battery cycling poses a considerable challenge, leading to performance degradation and safety hazards. This study aims to address this issue by investigating the effectiveness of a protective layer on the lithium metal surface in inhibiting dendrite growth. The hypothesis is that continuous lithium consumption during battery cycling is a primary contributor to dendrite formation. To test this hypothesis, a protective layer of Li₃Bi/Li₂O was applied to the lithium foil through immersion in a BiN₃O₉ solution. Experimental techniques including kelvin probe force microscopy (KPFM) and density functional theory (DFT) calculations were employed to analyze the structural and electronic properties of the Li₃Bi/Li₂O layer. The findings demonstrate successful doping of Bi into the Li coating, forming Bi-Bi and Bi-O bonds. KPFM measurements reveal a higher work function of Li₃Bi/Li₂O, indicating its potential as an effective protective layer. DFT calculations further support this observation by revealing a greater adsorption energy of lithium on the Li₃Bi/Li₂O layer compared to the bulk material. Charge density analysis suggests that the adsorption of Li atoms onto the Li₃Bi/Li₂O layer induces a redistribution of charge, resulting in increased electron availability on the surface and preventing electrode-electrolyte contact. This study provides insights into the role of the Li₃Bi/Li₂O protective layer in inhibiting dendrite growth in lithium metal batteries. By mitigating dendrite formation, the protective layer holds promise for enhancing battery performance and longevity. These findings contribute to the development of strategies for improving the stability and reliability of lithium metal batteries, facilitating their wider adoption in energy storage applications.

Keywords: Cycle stability; Density functional theory; Electric field; Li metal battery.