A zero energy-input nitrogen removal reactor based on a short-circuited microfluidic fuel cell

Abstract

Excessive discharge of ammonia nitrogen would deteriorate water quality. In this work, we designed an innovative microfluidic electrochemical nitrogen-removal reactor (MENR) based on a short-circuited ammonia-air microfluidic fuel cell (MFC). The MENR utilizes the laminar characteristics of two flows (an anolyte containing nitrogen-rich wastewater and a catholyte of acid electrolyte solution) in a microchannel to establish an efficient reactor system. At anode, ammonia was catalyzed by a NiCu/C modified electrode to N₂, while O₂ in the air was reduced at cathode. In essence, the MENR reactor is a short-circuited MFC. Maximum discharge currents were achieved accompanied with strong ammonia oxidation reaction. Factors indicating electrolyte flow rate, initial nitrogen concentration, electrolyte concentration, and electrode geometry have various effects on the nitrogen removal performance of the MENR. Results indicate that the MENR showed efficient nitrogen removal properties. This work proposes an energy-saving process by using the MENR to remove nitrogen from ammonia-rich wastewater.

Keywords: Ammonia oxidation reaction; NiCu/C modified electrode; Short-circuited microfluidic fuel cell; Zero energy-input nitrogen removal.