The carbon nanotubes (CNT) intercalated graphene oxide (GO) nanosheets was functionalized with molybdenum disulfide nanoparticles (MSNP). Intercalation of CNT in between GO nanosheets significantly enhances porosity and avail both surfaces of GO for MSNP decoration. High porosity and densely populated MSNP led to faster Hg(II) ions diffusion and sorption. The material shows high selectivity for Hg(II) sorption due to sulfur rich sites. The GO/CNT@MSNP packed column employed for trace Hg(II) preconcentration and determination in fish, rice, mushroom, sunflower seeds and river and ground water samples. No significant hindrances by co-existing matrices in the determination of Hg(II) was found. The method shows a preconcentration factor of 540 and a preconcentration limit of 0.37 μg L-1. The method detection limit was found to be 0.03 μg L-1 and a good precision (RSD 4.2%). The Student's t test score was lower than critical Student's t value of 4.303 at the 95% confidence level. ENVIRONMENTAL IMPLICATION: Metal ions toxicity is a global issue and their trace level analysis from complex matrices is remains challenging. SPE of trace Hg(II) by graphene oxide is challenging due to agglomeration and less selectivity, nevertheless of its high surface area. We prepared a Hg(II) selective nanocomposite of MoS2 quantum dots grows onto GO surface. The hybrid nanocomposite selectively adsorbed Hg(II) ions from complex sample matrices. Compared to a nascent GO membrane, it were more efficient to preconcentrate and determine Hg(II) from real samples and provide more accurate data for environmental monitoring and assessment of action plan to control the Hg(II) pollution.
Keywords: Food & Water; Graphene oxide; Molybdenum disulfide; Nanocomposite; Solid phase extraction.
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