A self-sacrificing template strategy: In-situ construction of bimetallic MOF-derived self-supported CuCoSe nanosheet arrays for high-performance supercapacitors

Wenrui Wu; Yue Yan; Yingsong Yu; Xing Wang; Tao Xu; Xianfu Li

doi:10.1016/j.jcis.2023.07.001

A self-sacrificing template strategy: In-situ construction of bimetallic MOF-derived self-supported CuCoSe nanosheet arrays for high-performance supercapacitors

J Colloid Interface Sci. 2023 Nov 15;650(Pt A):358-368. doi: 10.1016/j.jcis.2023.07.001. Epub 2023 Jul 1.

Authors

Wenrui Wu¹, Yue Yan¹, Yingsong Yu², Xing Wang¹, Tao Xu³, Xianfu Li⁴

Affiliations

¹ School of Chemical and Environmental Engineering, Anhui Polytechnic University, Wuhu 241000, China.
² Key Laboratory of Advanced Textile Materials and Manufacturing Technology Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China.
³ Department of Chemistry and Applied Biological Sciences, South Dakota School of Mines and Technology, Rapid City, SD 57701, USA.
⁴ School of Chemical and Environmental Engineering, Anhui Polytechnic University, Wuhu 241000, China. Electronic address: lixianfu@ahpu.edu.cn.

PMID: 37413870
DOI: 10.1016/j.jcis.2023.07.001

Abstract

Transition metal selenides (TMSs) are viewed as a prospective high-capacity electrode material for asymmetric supercapacitors (ASCs). However, the inability to expose sufficient active sites due to the limitation of the area involved in the electrochemical reaction severely limits their inherent supercapacitive properties. Herein, a self-sacrificing template strategy is developed to prepare self-supported CuCoSe (CuCoSe@rGO-NF) nanosheet arrays by in situ construction of copper-cobalt bimetallic organic framework (CuCo-MOF) on rGO-modified nickel foam (rGO-NF) and rational design of Se^2- exchange process. Nanosheet arrays with high specific surface area are considered to be ideal platforms for accelerating electrolyte penetration and exposing rich electrochemical active sites. As a result, the CuCoSe@rGO-NF electrode delivers a high specific capacitance of 1521.6 F/g at 1 A/g, good rate performance and an excellent capacitance retention of 99.5% after 6000 cycles. The assembled ASC device has a high energy density of 19.8 Wh kg^-1 at 750 W kg^-1 and an ideal capacitance retention of 86.2% after 6000 cycles. This proposed strategy offers a viable strategy for designing and constructing electrode materials with superior energy storage performance.

Keywords: CuCo-MOF; Nanosheet arrays; Self-sacrificing template; Self-supported; Transition metal selenides.