Vacuum-Assisted Self-Healing Amphiphilic Copolymer Membranes for Gas Separation

Yao-Wei Hong; Livy Laysandra; Yu-Cheng Chiu; Dun-Yen Kang

doi:10.1021/acsami.3c06518

Vacuum-Assisted Self-Healing Amphiphilic Copolymer Membranes for Gas Separation

ACS Appl Mater Interfaces. 2023 Jul 19;15(28):34075-34086. doi: 10.1021/acsami.3c06518. Epub 2023 Jul 6.

Authors

Yao-Wei Hong¹, Livy Laysandra², Yu-Cheng Chiu², Dun-Yen Kang¹

Affiliations

¹ Department of Chemical Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 10617, Taiwan.
² Department of Chemical Engineering, National Taiwan University of Science and Technology, No. 43, Sec. 4, Keelung Road, Taipei 106335, Taiwan.

PMID: 37411032
DOI: 10.1021/acsami.3c06518

Abstract

Membrane gas separation provides a multitude of benefits over alternative separation techniques, especially in terms of energy efficiency and environmental sustainability. While polymeric membranes have been extensively investigated for gas separations, their self-healing capabilities have often been neglected. In this work, we have developed innovative self-healing amphiphilic copolymers by strategically incorporating three functional segments: n-butyl acrylate (BA), N-(hydroxymethyl)acrylamide (NMA), and methacrylic acid (MAA). Utilizing these three functional components, we have synthesized two distinct amphiphilic copolymers, namely, AP_NMA (PBA_x-co-PNMA_y) and AP_MAA (PBA_x-co-PMAA_y). These copolymers have been meticulously designed for gas separation applications. During the creation of these amphiphilic copolymers, BA and NMA segments were selected due to their vital role in the ease of tuning mechanical and self-healing properties. The functional groups (-OH and -NH) present on the NMA segment interact with CO₂ through hydrogen bonding, thereby boosting CO₂/N₂ separation and achieving superior selectivity. We assessed the self-healing potential of these amphiphilic copolymer membranes using two distinct strategies: conventional and vacuum-assisted self-healing. In the vacuum-assisted approach, a robust vacuum pump generates a suction force, leading to the formation of a cone-like shape in the membrane. This formation allows common fracture sites to adhere and trigger the self-healing process. As a result, AP_NMA maintains its high gas permeability and CO₂/N₂ selectivity even after the vacuum-assisted self-healing operation. The ideal CO₂/N₂ selectivity of the AP_NMA membrane aligns closely with the commercially available PEBAX-1657 membrane (17.54 vs 20.09). Notably, the gas selectivity of the AP_NMA membrane can be readily restored after damage, in contrast to the PEBAX-1657 membrane, which loses its selectivity upon damage.

Keywords: CO2 capture; CO2 separation; amphiphilic copolymers; membrane gas separation; self-healing membrane; self-healing polymer.