ZnO-Doped gC3N4 Nanocapsules for Enhancing the Performance of Electroless NiP Coating-Mechanical, Corrosion Protection, and Antibacterial Properties

Fatma Nabhan; Eman M Fayyad; Mostafa H Sliem; Farah M Shurrab; Kamel Eid; Gheyath Nasrallah; Aboubakr M Abdullah

doi:10.1021/acsomega.2c07288

ZnO-Doped gC₃N₄ Nanocapsules for Enhancing the Performance of Electroless NiP Coating-Mechanical, Corrosion Protection, and Antibacterial Properties

ACS Omega. 2023 Jun 13;8(25):22361-22381. doi: 10.1021/acsomega.2c07288. eCollection 2023 Jun 27.

Authors

Fatma Nabhan¹, Eman M Fayyad¹, Mostafa H Sliem¹, Farah M Shurrab², Kamel Eid³, Gheyath Nasrallah², Aboubakr M Abdullah¹

Affiliations

¹ Center for Advanced Materials, Qatar University, Doha, Qatar 2713.
² Biomedical Research Center, Qatar University, Doha, Qatar 2713.
³ Gas Processing Center, Qatar University, Doha, Qatar 2713.

Abstract

A carbon nitride (C₃N₄) nanomaterial has superior mechanical, thermal, and tribological properties, which make them attractive for various applications, including corrosion-resistant coatings. In this research, newly synthesized C₃N₄ nanocapsules with different concentrations (0.5, 1.0, and 2.0 wt %) of ZnO as a dopant were incorporated into the NiP coating using an electroless deposition technique. The nanocomposite coatings either ZnO-doped (NiP-C₃N₄/ZnO) or undoped (NiP-C₃N₄) were heat-treated at 400 °C for 1 h. The as-plated and heat-treated (HT) nanocomposite coatings were characterized by their morphology, phases, roughness, wettability, hardness, corrosion protection, and antibacterial properties. The results indicated that the microhardness of as-plated and heat-treated nanocomposite coatings was significantly improved after the incorporation of 0.5 wt % ZnO-doped C₃N₄ nanocapsules. The outcomes of electrochemical studies revealed that the corrosion resistance of the HT coatings is higher than the corresponding as-plated ones. The highest corrosion resistance is achieved on the heat-treated NiP-C₃N₄/1.0 wt % ZnO coatings. Although the presence of ZnO in the C₃N₄ nanocapsules increased its surface area and porosity, the C₃N₄/ZnO nanocapsules prevented localized corrosion by filling the microdefects and pores of the NiP matrix. Furthermore, the colony-counting method used to evaluate the antibacterial behavior of the different coatings demonstrated superior antibacterial properties, namely, after heat treatment. Therefore, the novel perspective C₃N₄/ZnO nanocapsules can be utilized as a reinforcement nanomaterial in improving the mechanical and anticorrosion performance of NiP coatings in chloride media, together with providing superior antibacterial properties.