Flexible Ag-S-Te System with Promising Room-Temperature Thermoelectric Performance

Zhili Li; Jiye Zhang; Pengfei Luo; Jiayi Chen; Bowen Huang; Yuzhe Sun; Jun Luo

doi:10.1021/acsami.3c05688

Flexible Ag-S-Te System with Promising Room-Temperature Thermoelectric Performance

ACS Appl Mater Interfaces. 2023 Jul 19;15(28):33605-33611. doi: 10.1021/acsami.3c05688. Epub 2023 Jul 1.

Authors

Zhili Li¹, Jiye Zhang¹, Pengfei Luo¹, Jiayi Chen¹, Bowen Huang¹, Yuzhe Sun², Jun Luo^{1

3}

Affiliations

¹ School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China.
² Materials Genome Institute, Shanghai University, Shanghai 200444, China.
³ School of Materials Science and Engineering, Tongji University, Shanghai 201804, China.

PMID: 37392426
DOI: 10.1021/acsami.3c05688

Abstract

Silver chalcogenides demonstrate great potential as flexible thermoelectric materials due to their excellent ductility and tunable electrical and thermal transport properties. In this work, we report that the amorphous/crystalline phase ratio and thermoelectric properties of the Ag₂S_xTe_1-x (x = 0.55-0.75) samples can be modified by altering the S content. The room-temperature power factor of the Ag₂S_0.55Te_0.45 sample is 4.9 μW cm^-1 K^-2, and a higher power factor can be achieved by decreasing the carrier concentration as predicted by the single parabolic band model. The addition of a small amount of excessive Te into Ag₂S_0.55Te_0.45 (Ag₂S_0.55Te_0.45+y) not only enhances the power factor by decreasing the carrier concentration but also reduces the total thermal conductivity due to decreased electronic thermal conductivity. Owing to the effectively optimized carrier concentration, the thermoelectric power factor and dimensionless figure of merit zT of the sample with y = 0.007 reaches, respectively, 6.2 μW cm^-1 K^-2 and 0.39, while the excellent plastic deformability is well maintained, demonstrating its promising potential as a flexible thermoelectric material at room temperature.

Keywords: carrier concentration; ductile semiconductors; power factor; silver chalcogenides; thermoelectric materials.