Selective separation of metals from wastewater using sulfide precipitation: A critical review in agents, operational factors and particle aggregation

Abstract

Extensive research has been conducted on the separation and recovery of heavy metals from wastewater through the targeted precipitation of metal sulfides. It is necessary to integrate various factors to establish the internal correlation between sulfide precipitation and selective separation. This study provides a comprehensive review of the selective precipitation of metal sulfides, considering sulfur source types, operating factors, and particle aggregation. The controllable release of H₂S from insoluble metal sulfides has garnered research interest due to its potential for development. The pH value and sulfide ion supersaturation are identified as key operational factors influencing selectivity precipitation. Effective adjustment of sulfide concentration and feeding rate can reduce local supersaturation and improve separation accuracy. The particle surface potential and hydrophilic/hydrophobic properties are crucial factors affecting particle aggregation, and methods to enhance particle settling and filtration performance are summarized. The regulation of pH and sulfur ion saturation also controls the zeta potential and hydrophilic/hydrophobic properties on the particles surface, thereby affecting particle aggregation. Insoluble sulfides can decrease sulfur ion supersaturation and improve separation accuracy, but they can also promote particle nucleation and growth by acting as growth platforms and reducing energy barriers. The combined influence of sulfur source and regulation factors is vital for achieving precise separation of metal ions and particle aggregation. Finally, suggestions and prospects are proposed for the development of agents, kinetic optimization, and product utilization to promote the industrial application of selective precipitation of metal sulfides in a better, safer, and more efficient way.

Keywords: Aggregation; Separation accuracy; Slow-release sulfide; Sulfide precipitation; Supersaturation.