Industrial wastewater is categorized as a voracious consumer of fresh water and a high-strength source of pollution. Coagulation-flocculation is a simple and cost-effective technique for removing organic/inorganic compounds and colloidal particles from industrial effluents. Despite the outstanding natural properties, biodegradability, and efficacy of natural coagulants/flocculants (NC/Fs) in industrial wastewater treatment, their significant potential to remediate such effluents is underappreciated, particularly in commercial scale applications. Most reviews on NC/Fs focused on the possible application of plant-based sources such as plant seeds, tannin, certain vegetables/fruit peels, and their lab-scale potential. Our review expands the scope by examining the feasibility of using natural materials from other sources for industrial effluent decontamination. By analyzing the latest data on NC/Fs, we identify the most promising preparation techniques for making these materials stable enough to compete with traditional options in the marketplace. An interesting presentation of the results of various recent studies has also been highlighted and discussed. Additionally, we highlight the recent success of using magnetic-natural coagulants/flocculants (M-NC/Fs) in treating diverse industrial effluents, and discuss the potential for reprocessing spent materials as a renewable resource. The review also offers different concepts for suggested large-scale treatment systems used by MN-CFs.
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