A Ni(II) Coordination Polymer as a Multifunctional Luminescent Sensor for Detection of UO22+, Cr2O72-, CrO42- and Nitrofurantoin

Abstract

A new Ni coordination polymer [Ni(MIP)(BMIOPE)]_n (1) was constructed (BMIOPE = 4,4'-bis(2-methylimidazol-1-yl)diphenyl ether, and H₂MIP = 5-methylisophthalic acid), possessing two-dimensional (2D) twofold parallel interwoven net structure with a 4⁴∙6² point symbol. Complex 1 has been successfully obtained based on mixed-ligand strategy. The fluorescence titration experiments revealed that complex 1 could act as multifunctional luminescent sensor to simultaneously detect UO₂²⁺, Cr₂O₇^2- and CrO₄^2-, and NFT (nitrofurantoin). The limit of detection (LOD) values for complex 1 are 2.86 × 10^-5, 4.09 × 10^-5, 3.79 × 10^-5 and 9.32 × 10^-5 M for UO₂²⁺, Cr₂O₇^2-, CrO₄^2- and NFT. The K_sv values are 6.18 × 10³, 1.44 × 10⁴, 1.27 × 10⁴ and 1.51 × 10⁴ M^-1 for NFT, CrO₄^2-, Cr₂O₇^2- and UO₂²⁺. Finally, the mechanism of its luminescence sensing is studied in detail. These results manifest that complex 1 is a multifunctional sensor for sensitive fluorescent UO₂²⁺, Cr₂O₇^2-, CrO₄^2- and NFT detection.

Keywords: Cr2O72−/CrO42− sensing; UO22+ sensing; coordination polymer; luminescent sensor; nitrofurantoin sensing.